Self-hydroxylation of perbenzoic acids at a nonheme iron(II) center

Na Young Oh; Mi Sook Seo; Mi Hee Lim; Mark B. Consugar; Mi Joo Park; Jan-Uwe Rohde; Jaehong Han; Kwan Mook Kim; Jinheung Kim; Lawrence Que, Jr; Wonwoo Nam

doi:10.1039/B511302D

Self-hydroxylation of perbenzoic acids at a nonheme iron(ii) center†

Na Young Oh,^a Mi Sook Seo,^a Mi Hee Lim,^a Mark B. Consugar,^b Mi Joo Park,^a Jan-Uwe Rohde,^b Jaehong Han,^a Kwan Mook Kim,^a Jinheung Kim,^a Lawrence Que, Jr*^b and Wonwoo Nam*^a

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^a Department of Chemistry, Division of Nano Sciences and Center for Biomimetic Systems, Ewha Womans University, Seoul, Korea
E-mail: wwnam@ewha.ac.kr
Fax: +82 2 3277 4441
Tel: +82 2 3277 2392

^b Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, Minneapolis, Minnesota 55455, USA
E-mail: que@chem.umn.edu
Fax: +1 612 624 7029
Tel: +1 612 625 0389

Abstract

Treatment of mononuclear nonheme iron(II) complexes bearing two cis-labile sites with perbenzoic acids results in the self-hydroxylation of the aromatic ring to form the corresponding iron(III)–salicylate complexes through an intramolecular oxo-transfer process.

Chemical Communications

Self-hydroxylation of perbenzoic acids at a nonheme iron(ii) center†

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Self-hydroxylation of perbenzoic acids at a nonheme iron(II) center

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