Issue 1, 2006
From the journal:

Dalton Transactions

Synthesis of anionic methylpalladium complexes with phosphine–sulfonate ligands and their activities for olefin polymerization†

Takuya Kochi,a   Kenji Yoshimuraa  and  Kyoko Nozaki*a  

* Corresponding authors

a Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, Tokyo 113-8656, Japan
E-mail: nozaki@chembio.t.u-tokyo.ac.jp
Fax: +81 3 5341 7261
Tel: +81 3 5841 7261

Abstract

Reaction of diarylphosphinobenzene-2-sulfonic acids with tertially amines, followed by addition of [PdMeCl(cod)], provided anionic methylpalladium(II) complexes with bidentate phosphine–sulfonate ligands, which show high activity for copolymerization of ethylene with methyl acrylate.

Graphical abstract: Synthesis of anionic methylpalladium complexes with phosphine–sulfonate ligands and their activities for olefin polymerization

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Article information

DOI
https://doi.org/10.1039/B512452M
Article type
Communication
Submitted
02 Sep 2005
Accepted
31 Oct 2005
First published
14 Nov 2005

Dalton Trans., 2006, 25-27

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Synthesis of anionic methylpalladium complexes with phosphine–sulfonate ligands and their activities for olefin polymerization

T. Kochi, K. Yoshimura and K. Nozaki, Dalton Trans., 2006, 25 DOI: 10.1039/B512452M

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