The range of available arene dihydroxylating dioxygenase enzymes, their structure and mechanism, and recent examples of the application of arene cis-dihydrodiol bioproducts as chiral precursors in the synthesis of natural and unnatural products and chiral ligands are discussed.
D. R. Boyd and T. D. H. Bugg, Org. Biomol. Chem., 2006, 4, 181 DOI: 10.1039/B513226F
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