Issue 3, 2006
From the journal:

Chemical Communications

An insight into the protonation property of a diiron azadithiolate complex pertinent to the active site of Fe-only hydrogenases†

Weibing Dong,a   Mei Wang,*a   Xiaoyang Liu,ab   Kun Jin,a   Guanghua Li,b   Fujun Wanga  and  Licheng Sun*ac  

* Corresponding authors

a State Key Laboratory of Fine Chemicals, Dalian University of Technology, Zhongshan Road 158-46, 116012 Dalian, P. R. China
E-mail: symbueno@dlut.edu.cn
Fax: +86 411 83702185
Tel: +86 411 88993886

b State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, 130012 Changchun, P. R. China

c KTH Chemistry, Organic Chemistry, Royal Institute of Technology, 10044 Stockholm, Sweden

Abstract

Protonation of [{(μ-SCH2)2N(C6H4-p-NO2)}{Fe(CO)2(PMe3)}2] in the presence of 4 equiv. of HOTf afforded two species, a μ-hydride diiron complex, the molecular structure of which was crystallographically characterized, and a μ-S-protonated species, which was readily deprotonated in the presence of pyridine.

Graphical abstract: An insight into the protonation property of a diiron azadithiolate complex pertinent to the active site of Fe-only hydrogenases

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Article information

DOI
https://doi.org/10.1039/B513270C
Article type
Communication
Submitted
19 Sep 2005
Accepted
31 Oct 2005
First published
22 Nov 2005

Chem. Commun., 2006, 305-307

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An insight into the protonation property of a diiron azadithiolate complex pertinent to the active site of Fe-only hydrogenases

W. Dong, M. Wang, X. Liu, K. Jin, G. Li, F. Wang and L. Sun, Chem. Commun., 2006, 305 DOI: 10.1039/B513270C

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