Issue 17, 2006
From the journal:

Dalton Transactions

A scandium coordination polymer constructed from trimeric octahedral building blocks and 2,5-dihydroxyterephthalate

Pascal D. C. Dietzel,*ab   Richard Bloma  and  Helmer Fjellvågb  

* Corresponding authors

a SINTEF Materials and Chemistry, Postboks 124, Blindern, Oslo, Norway
E-mail: pascal.dietzel@sintef.no
Fax: +47 22067350
Tel: +47 22067411

b Centre for Materials Science and Nanotechnology, Department of Chemistry, University of Oslo, Postboks 1033, Blindern, Oslo, Norway

Abstract

Scandium chloride and nitrate react with 2,5-dihydroxyterephthalic acid to form three-dimensional framework compounds in which hexagonally-closed packed inorganic building blocks are linked by the carboxylate groups of the organic ligand. The inorganic moieties consist of three scandium oxygen octahedra that are joined by a common µ3-oxygen atom; the pores in the structure account for 60% of the volume, but the framework decomposes upon removal of the solvent molecules.

Graphical abstract: A scandium coordination polymer constructed from trimeric octahedral building blocks and 2,5-dihydroxyterephthalate

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Article information

DOI
https://doi.org/10.1039/B516365J
Article type
Communication
Submitted
18 Nov 2005
Accepted
01 Mar 2006
First published
13 Mar 2006

Dalton Trans., 2006, 2055-2057

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A scandium coordination polymer constructed from trimeric octahedral building blocks and 2,5-dihydroxyterephthalate

P. D. C. Dietzel, R. Blom and H. Fjellvåg, Dalton Trans., 2006, 2055 DOI: 10.1039/B516365J

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