Issue 5, 2006
From the journal:

Organic & Biomolecular Chemistry

Rhodium/phosphoramidite-catalyzed asymmetric arylation of aldehydes with arylboronic acids†

Richard B. C. Jagt,a   Patrick Y. Toullec,a   Johannes G. de Vries,*b   Ben L. Feringa*a  and  Adriaan J. Minnaard*a  

* Corresponding authors

a Department of Organic and Molecular Inorganic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, Groningen, The Netherlands
E-mail: a.j.minnaard@rug.nl, b.l.feringa@rug.nl

b DSM Research, Life Sciences-Advanced Synthesis & Catalysis, P.O. box 18, Geleen, The Netherlands

Abstract

Phosphoramidites are effective chiral ligands in the rhodium catalyzed addition of arylboronic acids to aldehydes providing up to 75% enantioselectivity and up to 96% isolated yield.

Graphical abstract: Rhodium/phosphoramidite-catalyzed asymmetric arylation of aldehydes with arylboronic acids

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Article information

DOI
https://doi.org/10.1039/B518311A
Article type
Communication
Submitted
03 Jan 2006
Accepted
21 Jan 2006
First published
31 Jan 2006

Org. Biomol. Chem., 2006,4, 773-775

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Rhodium/phosphoramidite-catalyzed asymmetric arylation of aldehydes with arylboronic acids

R. B. C. Jagt, P. Y. Toullec, J. G. de Vries, B. L. Feringa and A. J. Minnaard, Org. Biomol. Chem., 2006, 4, 773 DOI: 10.1039/B518311A

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