Issue 7, 2006
From the journal:

Organic & Biomolecular Chemistry

Thiocarbonyl compounds as regulating reagent in the radical addition of tertiary amines with alkenes using photoelectron transfer conditions†

Dominique Harakat,a   Jens Pesch,a   Siniša Marinkovića  and  Norbert Hoffmann*a  

* Corresponding authors

a Laboratoire des Réactions Sélectives et Applications, UMR CNRS et Université de Reims Champagne-Ardenne, UFR Sciences, B.P. 1039, F-51687 Reims, cedex 02, France
E-mail: norbert.hoffmann@univ-reims.fr
Fax: +33 (0)3 26 91 31 66
Tel: +33 (0)3 26 91 31 96

Abstract

The efficiency of the photoinduced radical addition of tertiary amines to olefinic double bonds is significantly enhanced and the stereoselectivity is influenced when thiocarbonyl compounds are added to the reaction mixture.

Graphical abstract: Thiocarbonyl compounds as regulating reagent in the radical addition of tertiary amines with alkenes using photoelectron transfer conditions

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Article information

DOI
https://doi.org/10.1039/B600220J
Article type
Communication
Submitted
09 Jan 2006
Accepted
01 Feb 2006
First published
14 Feb 2006

Org. Biomol. Chem., 2006,4, 1202-1205

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Thiocarbonyl compounds as regulating reagent in the radical addition of tertiary amines with alkenes using photoelectron transfer conditions

D. Harakat, J. Pesch, S. Marinković and N. Hoffmann, Org. Biomol. Chem., 2006, 4, 1202 DOI: 10.1039/B600220J

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