Issue 27, 2006
From the journal:

Chemical Communications

Design and solvothermal synthesis of luminescent copper(i)-pyrazolate coordination oligomer and polymer frameworks†

Jun He,a   Ye-Gao Yin,*a   Tao Wu,a   Dan Li*a  and  Xiao-Chun Huanga  

* Corresponding authors

a Department of Chemistry, Shantou University, Guangdong, P. R. China
E-mail: ygyin@stu.edu.cn, dli@stu.edu.cn
Fax: +86 754 290-2767
Tel: +86 754 290-3699

Abstract

Two luminescent coordination compounds, [Cu(Pz)]3 (1) and [Cu2(Bpz)]n (2), were isolated from solvothermal reactions of Cu(NO3)2 with 3,5-dimethylpyrazole (HPz) and 3,3′,5,5′-tetramethyl-4,4′-bipyrazole (H2Bpz) respectively in the presence of NH3, of which 1 was revealed to be a planar trimer and 2 a three-dimensional framework, presenting a rare 3-connected binodal (62.10)(6.102) topology and eight-fold interpenetration.

Graphical abstract: Design and solvothermal synthesis of luminescent copper(i)-pyrazolate coordination oligomer and polymer frameworks

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Article information

DOI
https://doi.org/10.1039/B601009A
Article type
Communication
Submitted
23 Jan 2006
Accepted
23 Feb 2006
First published
10 Mar 2006

Chem. Commun., 2006, 2845-2847

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Design and solvothermal synthesis of luminescent copper(I)-pyrazolate coordination oligomer and polymer frameworks

J. He, Y. Yin, T. Wu, D. Li and X. Huang, Chem. Commun., 2006, 2845 DOI: 10.1039/B601009A

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