Issue 27, 2006
From the journal:

Chemical Communications

Rapid phosphorus triester hydrolysis catalyzed by bimetallic tetrabenzimidazole complexes†

Kortney L. Klinkel,a   Lauren A. Kiemele,a   Douglas L. Gina  and  John R. Hagadorn*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado, USA
E-mail: hagadorn@colorado.edu
Fax: +1 303 492 5894
Tel: +1 303 492 5717

Abstract

Bimetallic complexes based on the binucleating ligand N,N,N′,N′-tetrakis[(2-benzimidazolyl)methyl]-2-hydroxy-1,3-diaminopropane (1L) and its new toluoyl ester derivative (2L) catalyze the hydrolysis of phosphorus triesters at ambient temperature with activities rivalling the fastest known systems.

Graphical abstract: Rapid phosphorus triester hydrolysis catalyzed by bimetallic tetrabenzimidazole complexes

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Article information

DOI
https://doi.org/10.1039/B602769E
Article type
Communication
Submitted
23 Feb 2006
Accepted
16 May 2006
First published
06 Jun 2006

Chem. Commun., 2006, 2919-2921

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Rapid phosphorus triester hydrolysis catalyzed by bimetallic tetrabenzimidazole complexes

K. L. Klinkel, L. A. Kiemele, D. L. Gin and J. R. Hagadorn, Chem. Commun., 2006, 2919 DOI: 10.1039/B602769E

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