Issue 19, 2006

AuI-catalyzed cycloisomerization of 1,5-enynes bearing a propargylic acetate: formation of unexpected bicyclo[3.1.0]hexene

Abstract

The use of N-heterocyclic carbene (NHC) as a ligand in the gold(I)-catalyzed cycloisomerization of enyne results in the assembly of a new carbocyclic product.

Graphical abstract: AuI-catalyzed cycloisomerization of 1,5-enynes bearing a propargylic acetate: formation of unexpected bicyclo[3.1.0]hexene

Article information

Article type
Communication
Submitted
24 Feb 2006
Accepted
13 Mar 2006
First published
13 Apr 2006

Chem. Commun., 2006, 2048-2050

AuI-catalyzed cycloisomerization of 1,5-enynes bearing a propargylic acetate: formation of unexpected bicyclo[3.1.0]hexene

N. Marion, P. de Frémont, G. Lemière, E. D. Stevens, L. Fensterbank, M. Malacria and S. P. Nolan, Chem. Commun., 2006, 2048 DOI: 10.1039/B602839J

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