A key step in the formation of acrylic acid from CO2 and ethylene: the transformation of a nickelalactone into a nickel-acrylate complex

Reinald Fischer; Jens Langer; Astrid Malassa; Dirk Walther; Helmar Görls; Gavin Vaughan

doi:10.1039/B603540J

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A key step in the formation of acrylic acid from CO₂ and ethylene: the transformation of a nickelalactone into a nickel-acrylate complex†

Reinald Fischer,^a Jens Langer,^a Astrid Malassa,^a Dirk Walther,*^a Helmar Görls^a and Gavin Vaughan^b

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* Corresponding authors

^a Department of Inorganic and Analytical Chemistry, University of Jena, Germany
E-mail: Dirk.Walther@uni-jena.de

^b European Synchrotron Radiation Facility (ESRF), 6 rue Jules Horowitz, BP220, France

Abstract

The reaction of a nickelalactone with dppm, resulting in the formation of a stable binuclear Ni(I) complex with an acrylate, a Ph₂P⁻ and a dppm bridge, models a key step in the formation of acrylic acid from CO₂ and ethylene.

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Article information

DOI: https://doi.org/10.1039/B603540J
Article type: Communication
Submitted: 08 Mar 2006
Accepted: 20 Apr 2006
First published: 09 May 2006

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Chem. Commun., 2006, 2510-2512

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A key step in the formation of acrylic acid from CO₂ and ethylene: the transformation of a nickelalactone into a nickel-acrylate complex

R. Fischer, J. Langer, A. Malassa, D. Walther, H. Görls and G. Vaughan, Chem. Commun., 2006, 2510 DOI: 10.1039/B603540J

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