Issue 23, 2006
From the journal:

Chemical Communications

Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)4(H2O)(η1-OSO)][MeC6H4SO3]2

Katharine F. Bowes,a   Jacqueline M. Cole,*a   Shamus L. G. Husheer,a   Paul R. Raithby,*bc   Teresa L. Savarese,b   Hazel A. Sparkes,b   Simon J. Teatd  and  John E. Warrenc  

* Corresponding authors

a Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UK
E-mail: jmc61@cam.ac.uk

b Department of Chemistry, University of Bath, Claverton Down, Bath, UK
E-mail: p.r.raithby@bath.ac.uk

c CCLRC Daresbury Laboratory, Daresbury, Warrington, UK

d Diamond Light Source, Rutherford Appleton Laboratories, Chilton, Didcot, Oxon, UK

Abstract

The structure of a new metastable geometric isomer of [Ru(NH3)4(H2O)(SO2)][MeC6H4SO3]2 in which the SO2 group is coordinated through a single oxygen in an η1-OSO bonding mode has been determined at 13 K; the new isomer was obtained as a 36% component of the structure within a single crystal upon irradiation using a tungsten lamp.

Graphical abstract: Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)4(H2O)(η1-OSO)][MeC6H4SO3]2

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Article information

DOI
https://doi.org/10.1039/B604039J
Article type
Communication
Submitted
20 Mar 2006
Accepted
21 Apr 2006
First published
04 May 2006

Chem. Commun., 2006, 2448-2450

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Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)4(H2O)(η1-OSO)][MeC6H4SO3]2

K. F. Bowes, J. M. Cole, S. L. G. Husheer, P. R. Raithby, T. L. Savarese, H. A. Sparkes, S. J. Teat and J. E. Warren, Chem. Commun., 2006, 2448 DOI: 10.1039/B604039J

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