Issue 36, 2006
From the journal:

Chemical Communications

Early–late heterobimetallic complexes as initiator for ethylenepolymerization. Cooperative effect of two metal centers to afford highly branched polyethylene†

Junpei Kuwabara,a   Daisuke Takeuchia  and  Kohtaro Osakada*a  

* Corresponding authors

a Chemical Resources Laboratory (R1-03), Tokyo Institute of Technology, 4259 Nagatsuta, Yokohama, Japan
E-mail: kosakada@res.titech.ac.jp
Fax: +81-45-924-5224
Tel: +81-45-924-5224

Abstract

Ethylene polymerization initiated by early–late transition-metal complexes afforded a polymer with different branched structures and properties depending on the type of late transition-metal.

Graphical abstract: Early–late heterobimetallic complexes as initiator for ethylene polymerization. Cooperative effect of two metal centers to afford highly branched polyethylene

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Article information

DOI
https://doi.org/10.1039/B605800K
Article type
Communication
Submitted
24 Apr 2006
Accepted
06 Jul 2006
First published
03 Aug 2006

Chem. Commun., 2006, 3815-3817

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Early–late heterobimetallic complexes as initiator for ethylene polymerization. Cooperative effect of two metal centers to afford highly branched polyethylene

J. Kuwabara, D. Takeuchi and K. Osakada, Chem. Commun., 2006, 3815 DOI: 10.1039/B605800K

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