Issue 32, 2006
From the journal:

Chemical Communications

Unprecedented formation of an acetamidate-bridged dinuclear platinum(ii) terpyridyl complex—correlation of luminescence properties with the crystal forms and dimerization studies in solution†

Keith Man-Chung Wong,*a   Nianyong Zhua  and  Vivian Wing-Wah Yam*a  

* Corresponding authors

a Department of Chemistry and HKU-CAS Joint Laboratory on New Materials, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China
E-mail: wongmc@hku.hk, wwyam@hku.hk
Fax: +852 2857-1586
Tel: +852 2859-2153

Abstract

An unprecedented acetamidate-bridged dinuclear platinum(II) terpyridyl complex has been isolated in two crystal forms, a red form and a dark form, with different luminescence properties; electronic absorption, emission and 1H NMR studies revealed the presence of a dimerization process in the solution state.

Graphical abstract: Unprecedented formation of an acetamidate-bridged dinuclear platinum(ii) terpyridyl complex—correlation of luminescence properties with the crystal forms and dimerization studies in solution

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Article information

DOI
https://doi.org/10.1039/B606352G
Article type
Communication
Submitted
04 May 2006
Accepted
08 Jun 2006
First published
10 Jul 2006

Chem. Commun., 2006, 3441-3443

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Unprecedented formation of an acetamidate-bridged dinuclear platinum(II) terpyridyl complex—correlation of luminescence properties with the crystal forms and dimerization studies in solution

K. M. Wong, N. Zhu and V. W. Yam, Chem. Commun., 2006, 3441 DOI: 10.1039/B606352G

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