NiII(TPA) as an efficient catalyst for alkane hydroxylation with m-CPBA

Takayuki Nagataki; Yoshimitsu Tachi; Shinobu Itoh

doi:10.1039/B608311K

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Ni^II(TPA) as an efficient catalyst for alkanehydroxylation with m-CPBA†

Takayuki Nagataki,^a Yoshimitsu Tachi^a and Shinobu Itoh*^a

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^a Department of Chemistry, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka, Japan
E-mail: shinobu@sci.osaka-cu.ac.jp
Fax: +81-6-6605-2564
Tel: +81-6-6605-2564

Abstract

A simple Ni^II(TPA) complex [TPA = tris(2-pyridylmethyl)amine] has been demonstrated to act as an efficient turnover catalyst for alkane hydroxylation with m-CPBA (m-chloroperbenzoic acid), in which contribution of a NiO⁺ (nickel-oxo) type active oxygen species is suggested.

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Article information

DOI: https://doi.org/10.1039/B608311K
Article type: Communication
Submitted: 13 Jun 2006
Accepted: 01 Aug 2006
First published: 16 Aug 2006

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Chem. Commun., 2006, 4016-4018

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Ni^II(TPA) as an efficient catalyst for alkane hydroxylation with m-CPBA

T. Nagataki, Y. Tachi and S. Itoh, Chem. Commun., 2006, 4016 DOI: 10.1039/B608311K

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