Recent developments in the field of organic heterobimetallic compounds of the alkaline-earth metals

Abstract

Heterobimetallic compounds of the alkaline-earth metals show a wide structural variety with strongly differing reactivity patterns. The combination of magnesium and alkali metal amides yields cyclic molecules with an extreme high reactivity which often are considered as “inverse crowns” with the metal atoms as coordination sites for Lewis bases. In other metallates of the alkaline-earth metals an activation of alkyl groups succeeds. In alkaline-earth metal zincates an inverse coordination of the type M₂[(μ-R)₂ZnR]₂ is observed and the alkyl groups are in bridging positions between zinc and the s-block metals thus forming a very reactive M–C–Zn three-center–two-electron bond. Furthermore, the metals of the carbon group form alkaline-earth metal–silicon, –germanium and –tin bonds or, in the presence of very strong Lewis bases, even solvent-separated ion pairs. For electronegative substituents at tin an inverse coordination mode such as M[(µ-R)₂SnR]₂ is observed.