Issue 40, 2006
From the journal:

Physical Chemistry Chemical Physics

Quantitative chirality synchronization in trifluoroethanol dimers†‡

Tina Scharge,a   Thomas Häber§a  and  Martin A. Suhm*a  

* Corresponding authors

a Institut für Physikalische Chemie, Universität Göttingen, Tammannstr. 6, Göttingen, Germany
E-mail: msuhm@gwdg.de

Abstract

2,2,2-Trifluoroethanol molecules synchronize their transiently chiral gauche configurations upon dimerization in supersonic jet expansions, while they avoid an energetically competitive heteroconfigurational hydrogen bonded dimer topology predicted by extensive quantum chemical calculations.

Graphical abstract: Quantitative chirality synchronization in trifluoroethanol dimers

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Article information

DOI
https://doi.org/10.1039/B609868A
Article type
Communication
Submitted
12 Jul 2006
Accepted
05 Sep 2006
First published
21 Sep 2006

Phys. Chem. Chem. Phys., 2006,8, 4664-4667

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Quantitative chirality synchronization in trifluoroethanol dimers

T. Scharge, T. Häber and M. A. Suhm, Phys. Chem. Chem. Phys., 2006, 8, 4664 DOI: 10.1039/B609868A

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