Issue 41, 2006
From the journal:

Chemical Communications

A mechanistic rationalization of unusual kinetic behavior in proline-mediated C–O and C–N bond-forming reactions†

Suju P. Mathew,a   Martin Klussmann,a   Hiroshi Iwamura,‡a   David H. Wells, Jr.,§a   Alan Armstronga  and  Donna G. Blackmond*ab  

* Corresponding authors

a Department of Chemistry, Imperial College, London, UK
E-mail: d.blackmond@imperial.ac.uk
Fax: +44 (0)20 7594 5804
Tel: +44 (0)20 7594 1193

b Department of Chemical Engineering and Chemical Technology, Imperial College, London, UK

Abstract

Kinetic evidence supports the role of the reaction product in the catalytic cycle of proline-mediated α-aminoxylation and α-amination reactions, providing both design principles as well as a model for the evolution of efficiency in catalysis.

Graphical abstract: A mechanistic rationalization of unusual kinetic behavior in proline-mediated C–O and C–N bond-forming reactions

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Article information

DOI
https://doi.org/10.1039/B609926B
Article type
Communication
Submitted
12 Jul 2006
Accepted
10 Aug 2006
First published
31 Aug 2006

Chem. Commun., 2006, 4291-4293

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A mechanistic rationalization of unusual kinetic behavior in proline-mediated C–O and C–N bond-forming reactions

S. P. Mathew, M. Klussmann, H. Iwamura, D. H. Wells, Jr., A. Armstrong and D. G. Blackmond, Chem. Commun., 2006, 4291 DOI: 10.1039/B609926B

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