Issue 41, 2006

Electron transfer switching in supramolecular porphyrin–fullerene conjugates held by alkylammonium cation-crown ether binding

Abstract

Reversible switching between intra- to intermolecular electron transfer paths has been accomplished by adding and extracting potassium ions to the supramolecular porphyrinfullerene conjugates formed by complexing porphyrin functionalized with a benzo-18-crown-6 entity and fullerene functionalized with an alkylammonium cation entity.

Graphical abstract: Electron transfer switching in supramolecular porphyrin–fullerene conjugates held by alkylammonium cation-crown ether binding

Supplementary files

Article information

Article type
Communication
Submitted
16 Jul 2006
Accepted
11 Aug 2006
First published
06 Sep 2006

Chem. Commun., 2006, 4327-4329

Electron transfer switching in supramolecular porphyrinfullerene conjugates held by alkylammonium cation-crown ether binding

A. S. D. Sandanayaka, Y. Araki, O. Ito, R. Chitta, S. Gadde and F. D'Souza, Chem. Commun., 2006, 4327 DOI: 10.1039/B610171B

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