Issue 46, 2006

Reductive disproportionation of carbon dioxide by a Sm(ii) complex: Unprecedented f-block element reactivity giving a carbonate complex

Abstract

A macrocyclic organosamarium(II) complex has been shown to provide the first example of the reductive disproportionation of carbon dioxide, giving a bimetallic carbonate complex and carbon monoxide in a facile reaction under ambient conditions.

Graphical abstract: Reductive disproportionation of carbon dioxide by a Sm(ii) complex: Unprecedented f-block element reactivity giving a carbonate complex

Supplementary files

Article information

Article type
Communication
Submitted
15 Aug 2006
Accepted
08 Sep 2006
First published
04 Oct 2006

Chem. Commun., 2006, 4853-4855

Reductive disproportionation of carbon dioxide by a Sm(II) complex: Unprecedented f-block element reactivity giving a carbonate complex

N. W. Davies, A. S. P. Frey, M. G. Gardiner and J. Wang, Chem. Commun., 2006, 4853 DOI: 10.1039/B611784H

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