Issue 4, 2007
From the journal:

Chemical Communications

The P(bth)2− anion as a Janus head staple between lithium and manganese (bth = benzothiazol-2-yl, C7H4NS)

Thomas Stey,a   Julian Henna  and  Dietmar Stalke*a  

* Corresponding authors

a Institut für Anorganische Chemie der Universität Göttingen, Tammannstraße 4, Göttingen, Germany
E-mail: dstalke@chemie.uni-goettingen.de
Fax: +49-551-39-3459
Tel: +49-551-39-3000

Abstract

Deprotonation of HP(bth)2 (1) affords the lithium phosphanide [(Et2O)2Li(bth)2P], (2) with both nitrogen atoms coordinated to the lithium atom while in the heterobimetallic complex [Li(bth)2P{Mn(CO)2Cp}2]n (3) additionally the phosphorus atom μ-bridges two Mn(CO)2Cp residues.

Graphical abstract: The P(bth)2− anion as a Janus head staple between lithium and manganese (bth = benzothiazol-2-yl, C7H4NS)

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Article information

DOI
https://doi.org/10.1039/B612247G
Article type
Communication
Submitted
25 Aug 2006
Accepted
02 Oct 2006
First published
30 Oct 2006

Chem. Commun., 2007, 413-415

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The P(bth)2− anion as a Janus head staple between lithium and manganese (bth = benzothiazol-2-yl, C7H4NS)

T. Stey, J. Henn and D. Stalke, Chem. Commun., 2007, 413 DOI: 10.1039/B612247G

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