Cross-coupling of alkyl halides with Grignard reagents using nickel and palladium complexes bearing η3-allyl ligand as catalysts

Jun Terao; Yoshitaka Naitoh; Hitoshi Kuniyasu; Nobuaki Kambe

doi:10.1039/B612586G

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Cross-coupling of alkyl halides with Grignard reagents using nickel and palladium complexes bearing η³-allyl ligand as catalysts†

Jun Terao,*^a Yoshitaka Naitoh,^b Hitoshi Kuniyasu^b and Nobuaki Kambe*^b

Author affiliations

* Corresponding authors

^a Science and Technology Centre for Atoms, Molecules and Ions Control, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka, Japan
E-mail: terao@chem.eng.osaka-u.ac.jp
Fax: +81-6-6879-7390
Tel: +81-6-6879-7389

^b Department of Applied Chemistry Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka, Japan
E-mail: kambe@chem.eng.osaka-u.ac.jp
Fax: +81-6-6879-7390
Tel: +81-6-6879-7388

Abstract

The cross-coupling of Grignard reagents with alkyl bromides and tosylates has been achieved by the use of η³-allylnickel and η³-allylpalladium complexes as catalysts.

Download options Please wait...

Supplementary files

Typical experimental procedures and analytical data of products PDF (154K)

Article information

DOI: https://doi.org/10.1039/B612586G
Article type: Communication
Submitted: 01 Sep 2006
Accepted: 31 Oct 2006
First published: 21 Nov 2006

Download Citation

Chem. Commun., 2007, 825-827

Permissions

Request permissions

Cross-coupling of alkyl halides with Grignard reagents using nickel and palladium complexes bearing η³-allyl ligand as catalysts

J. Terao, Y. Naitoh, H. Kuniyasu and N. Kambe, Chem. Commun., 2007, 825 DOI: 10.1039/B612586G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications