Issue 7, 2007

Gold(i)-catalysed arylation of 1,6-enynes: different site reactivity of cyclopropyl gold carbenes

Abstract

Gold(I)-catalysed addition of electron-rich arenes and heteroarenes to 1,6-enynes gives two different types of products by reaction of the intermediate cyclopropyl gold carbenes at the cyclopropane or at the carbene.

Graphical abstract: Gold(i)-catalysed arylation of 1,6-enynes: different site reactivity of cyclopropyl gold carbenes

Supplementary files

Article information

Article type
Communication
Submitted
23 Oct 2006
Accepted
15 Nov 2006
First published
19 Dec 2006

Chem. Commun., 2007, 698-700

Gold(I)-catalysed arylation of 1,6-enynes: different site reactivity of cyclopropyl gold carbenes

C. H. M. Amijs, C. Ferrer and A. M. Echavarren, Chem. Commun., 2007, 698 DOI: 10.1039/B615335F

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