Issue 6, 2007
From the journal:

Physical Chemistry Chemical Physics

Autoxidation catalysis with N-hydroxyimides: more-reactive radicals or just more radicals?†

Ive Hermans,*a   Pierre Jacobsa  and  Jozef Peetersb  

* Corresponding authors

a Centre for Surface Chemistry and Catalysis, K. U. Leuven, Kasteelpark Arenberg 23, Heverlee, Belgium
E-mail: ive.hermans@biw.kuleuven.be
Fax: +32(0)16321998
Tel: +32(0)16321648

b Department of Chemistry, K. U. Leuven, Celestijnenlaan 200F, Heverlee, Belgium

Abstract

A first-principles analysis reveals that the catalytic efficiency of nitroxyl radicals in alkane oxidations is not simply correlated with their reactivity toward the substrate.

Graphical abstract: Autoxidation catalysis with N-hydroxyimides: more-reactive radicals or just more radicals?

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Article information

DOI
https://doi.org/10.1039/B616392K
Article type
Communication
Submitted
09 Nov 2006
Accepted
07 Dec 2006
First published
02 Jan 2007

Phys. Chem. Chem. Phys., 2007,9, 686-690

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Autoxidation catalysis with N-hydroxyimides: more-reactive radicals or just more radicals?

I. Hermans, P. Jacobs and J. Peeters, Phys. Chem. Chem. Phys., 2007, 9, 686 DOI: 10.1039/B616392K

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