Issue 7, 2007
From the journal:

Chemical Communications

An iron-catalysed hydrosilylation of ketones

Hisao Nishiyama*a  and  Akihiro Furutaa  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Chikusa, Nagoya, Japan
E-mail: hnishi@apchem.nagoya-u.ac.jp
Fax: 81 52 789 3209

Abstract

The combination of Fe(OAc)2 and multi-nitrogen-based ligands such as N,N,N′,N′-tetramethyethylenediamine, bis-tert-butyl-bipyridine, or bis(oxazolinyl)pyridine can efficiently catalyse hydrosilylation of ketones to give the corresponding alcohols in high yields including asymmetric catalysis.

Graphical abstract: An iron-catalysed hydrosilylation of ketones

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Article information

DOI
https://doi.org/10.1039/B617388H
Article type
Communication
Submitted
28 Nov 2006
Accepted
07 Dec 2006
First published
20 Dec 2006

Chem. Commun., 2007, 760-762

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An iron-catalysed hydrosilylation of ketones

H. Nishiyama and A. Furuta, Chem. Commun., 2007, 760 DOI: 10.1039/B617388H

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