Issue 15, 2007

Electropolymeric materials incorporating subsite structures related to iron-only hydrogenase: active ester functionalised poly(pyrroles) for covalent binding of {2Fe3S}-carbonyl/cyanide assemblies

Abstract

We report the assembly of the first electropolymeric materials incorporating catalytic diiron subsites related to those of the iron-only hydrogenases.

Graphical abstract: Electropolymeric materials incorporating subsite structures related to iron-only hydrogenase: active ester functionalised poly(pyrroles) for covalent binding of {2Fe3S}-carbonyl/cyanide assemblies

Supplementary files

Article information

Article type
Communication
Submitted
29 Nov 2006
Accepted
08 Jan 2007
First published
30 Jan 2007

Chem. Commun., 2007, 1535-1537

Electropolymeric materials incorporating subsite structures related to iron-only hydrogenase: active ester functionalised poly(pyrroles) for covalent binding of {2Fe3S}-carbonyl/cyanide assemblies

S. K. Ibrahim, X. Liu, C. Tard and C. J. Pickett, Chem. Commun., 2007, 1535 DOI: 10.1039/B617399C

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