Issue 17, 2007
From the journal:

Chemical Communications

Aryl bromide/triflate selectivities reveal mechanistic divergence in palladium-catalysed couplings; the Suzuki–Miyaura anomaly†

Gustavo Espino,a   Almira Kurbangalievaa  and  John M. Brown*a  

* Corresponding authors

a Chemistry Research Laboratory, Mansfield Rd., Oxford, UK
E-mail: john.brown@chem.ox.ac.uk
Fax: 44 1865 285002
Tel: 44 1865 275642

Abstract

In palladium-catalysed cross-coupling reactions, the outcome of competition between aryl bromides and aryl triflates depends on the nucleophilic partner; Suzuki couplings with R–B generally follow a different pattern from other R–M species.

Graphical abstract: Aryl bromide/triflate selectivities reveal mechanistic divergence in palladium-catalysed couplings; the Suzuki–Miyaura anomaly

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Article information

DOI
https://doi.org/10.1039/B701517H
Article type
Communication
Submitted
31 Jan 2007
Accepted
26 Mar 2007
First published
05 Apr 2007

Chem. Commun., 2007, 1742-1744

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Aryl bromide/triflate selectivities reveal mechanistic divergence in palladium-catalysed couplings; the Suzuki–Miyaura anomaly

G. Espino, A. Kurbangalieva and J. M. Brown, Chem. Commun., 2007, 1742 DOI: 10.1039/B701517H

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