Issue 21, 2007
From the journal:

Chemical Communications

Lewis acidity enhancement of organoboranes viaoxidation of appended ferrocene moieties†

Krishnan Venkatasubbaiah,a   Israel Nowik,b   Rolfe H. Herberb  and  Frieder Jäkle*a  

* Corresponding authors

a Rutgers University, 73 Warren Street, Newark, USA
E-mail: fjaekle@rutgers.edu
Fax: +1 973 353 5064
Tel: +1 973 353 1264

b Condensed Matter Physics Group, Racah Institute of Physics, The Hebrew University, Israel
E-mail: herber@vms.huji.ac.il
Fax: +972 2 6586347
Tel: +972 2 6584244

Abstract

The Lewis acidity of boron in diboradiferrocene 1 is strongly enhanced through oxidation of the iron atoms as evident from examination of X-ray structural parameters of the mixed-valent cation 1+PF6 and further confirmed from the strong complexation of MeCN to the dication in 22+(I3)2.

Graphical abstract: Lewis acidity enhancement of organoboranes via oxidation of appended ferrocene moieties

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Article information

DOI
https://doi.org/10.1039/B701807J
Article type
Communication
Submitted
08 Feb 2007
Accepted
10 Apr 2007
First published
01 May 2007

Chem. Commun., 2007, 2154-2156

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Lewis acidity enhancement of organoboranes via oxidation of appended ferrocene moieties

K. Venkatasubbaiah, I. Nowik, R. H. Herber and F. Jäkle, Chem. Commun., 2007, 2154 DOI: 10.1039/B701807J

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