Issue 30, 2007

Li2MnO3-stabilized LiMO2 (M = Mn, Ni, Co) electrodes for lithium-ion batteries

Abstract

A strategy used to design high capacity (>200 mAh g−1), Li2MnO3-stabilized LiMO2 (M = Mn, Ni, Co) electrodes for lithium-ion batteries is discussed. The advantages of the Li2MnO3 component and its influence on the structural stability and electrochemical properties of these layered xLi2MnO3·(1 − x)LiMO2 electrodes are highlighted. Structural, chemical, electrochemical and thermal properties of xLi2MnO3·(1 − x)LiMO2 electrodes are considered in the context of other commercially exploited electrode systems, such as LiCoO2, LiNi0.8Co0.15Al0.05O2, Li1+xMn2−xO4 and LiFePO4.

Graphical abstract: Li2MnO3-stabilized LiMO2 (M = Mn, Ni, Co) electrodes for lithium-ion batteries

Article information

Article type
Feature Article
Submitted
16 Feb 2007
Accepted
29 Mar 2007
First published
20 Apr 2007

J. Mater. Chem., 2007,17, 3112-3125

Li2MnO3-stabilized LiMO2 (M = Mn, Ni, Co) electrodes for lithium-ion batteries

M. M. Thackeray, S. Kang, C. S. Johnson, J. T. Vaughey, R. Benedek and S. A. Hackney, J. Mater. Chem., 2007, 17, 3112 DOI: 10.1039/B702425H

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