Issue 28, 2007
From the journal:

Chemical Communications

Hydrogen storage using polymer-supported organometallic dihydrogen complexes: a mechanistic study†

Andrew I. Cooper*a  and  Martyn Poliakoffb  

* Corresponding authors

a Department of Chemistry, University of Liverpool, Crown Street, Liverpool, UK
E-mail: aicooper@liv.ac.uk
Fax: +44 151 7942304
Tel: +44 151 7943548

b School of Chemistry, University of Nottingham, UK
E-mail: martyn.poliakoff@nottingham.ac.uk
Fax: +44 9513058

Abstract

The dihydrogen complex W(CO)5(H2) can be both generated and dissociated in polymer matrices by UV photolysis at 220 K and 90 K, respectively, suggesting a potential “UV-activated” mechanism for hydrogen storage and release.

Graphical abstract: Hydrogen storage using polymer-supported organometallic dihydrogen complexes: a mechanistic study

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Article information

DOI
https://doi.org/10.1039/B703701E
Article type
Communication
Submitted
12 Mar 2007
Accepted
12 Apr 2007
First published
10 May 2007

Chem. Commun., 2007, 2965-2967

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Hydrogen storage using polymer-supported organometallic dihydrogen complexes: a mechanistic study

A. I. Cooper and M. Poliakoff, Chem. Commun., 2007, 2965 DOI: 10.1039/B703701E

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