Issue 11, 2007
From the journal:

New Journal of Chemistry

Synthesis and characterization of a TTF-π-verdazyl radical—a new building block for conducting and/or magnetic systems

M’hamed Chahma,a   Keely Macnamara,a   Art van der Est,a   Antonio Alberola,b   Victor Polob  and  Melanie Pilkington*a  

* Corresponding authors

a Department of Chemistry, Brock University, 500 Glenridge Avenue, St. Catharines, Ontario, Canada
E-mail: mpilkington@brocku.ca
Fax: +1 905 682 9020
Tel: +1 905 688 5550; Ext. 3403

b Dpto. de Quimica Fisica y Analitica, Universitat Jaume I, Avda. Sos Baynat s/n, Castellón, Spain

Abstract

The synthetic strategy for the preparation of a TTF donor, π-appended with a spin bearing verdazyl radical has been developed. UV-Vis, electrochemical and EPR studies reveal that this is an attractive magnetic building block for subsequent oxidation that could afford new conducting and/or magnetic systems.

Graphical abstract: Synthesis and characterization of a TTF-π-verdazyl radical—a new building block for conducting and/or magnetic systems

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Article information

DOI
https://doi.org/10.1039/B706049A
Article type
Paper
Submitted
24 Apr 2007
Accepted
18 Jul 2007
First published
06 Aug 2007

New J. Chem., 2007,31, 1973-1978

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Synthesis and characterization of a TTF-π-verdazyl radical—a new building block for conducting and/or magnetic systems

M. Chahma, K. Macnamara, A. van der Est, A. Alberola, V. Polo and M. Pilkington, New J. Chem., 2007, 31, 1973 DOI: 10.1039/B706049A

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