In a computational investigation, dinuclear and tetranuclear copper acetylide complexes display both superior stability and higher reactivity in the CuAAC reaction than do mononuclear complexes due to favored dicopper(I,III) µ-alkenylidene fragments, instead of ring strain in a Cu![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
CC intermediate.
B. F. Straub, Chem. Commun., 2007, 3868 DOI: 10.1039/B706926J
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