Issue 36, 2007
From the journal:

Chemical Communications

A reversible metal–ligand bond break associated to a spin-crossover

Philippe Guionneau,*a   Frédéric Le Gac,a   Abdellah Kaiba,a   José Sánchez Costa,a   Daniel Chasseaua  and  Jean-François Létarda  

* Corresponding authors

a ICMCB, CNRS, Université Bordeaux 1, 87 avenue du Dr A. Schweitzer, Pessac cedex, France
E-mail: guio@icmcb-bordeaux.cnrs.fr

Abstract

The [FeIIL(CN)2]·H2O complex, dicyano[2,13-dimethyl-6,9-dioxa-3,12,18-triazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene]iron(II) monohydrate, exhibits a thermal induced metal–ligand bond break reversible in the solid state and associated to a spin crossover that corresponds to an unprecedented structurally characterized modification of the coordination metal environment from a hepta-coordinate high spin state to a hexa-coordinate low spin state.

Graphical abstract: A reversible metal–ligand bond break associated to a spin-crossover

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Article information

DOI
https://doi.org/10.1039/B707836F
Article type
Communication
Submitted
23 May 2007
Accepted
25 Jun 2007
First published
09 Jul 2007

Chem. Commun., 2007, 3723-3725

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A reversible metal–ligand bond break associated to a spin-crossover

P. Guionneau, F. Le Gac, A. Kaiba, J. S. Costa, D. Chasseau and J. Létard, Chem. Commun., 2007, 3723 DOI: 10.1039/B707836F

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