The highest nuclearity metal oxime clusters: Ni14 and Ni12Na2 complexes from the use of 2-pyridinealdoximate and azide ligands

Theocharis C. Stamatatos; Khalil A. Abboud; Spyros P. Perlepes; George Christou

doi:10.1039/B708189H

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The highest nuclearity metal oxime clusters: Ni₁₄ and Ni₁₂Na₂ complexes from the use of 2-pyridinealdoximate and azide ligands†‡

Theocharis C. Stamatatos,^a Khalil A. Abboud,^a Spyros P. Perlepes^b and George Christou*^a

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* Corresponding authors

^a Department of Chemistry, University of Florida, Gainesville, Florida, USA
E-mail: christou@chem.ufl.edu
Fax: +1 352-392-6737
Tel: +1 352-392-8314

^b Department of Chemistry, University of Patras, Patras, Greece

Abstract

The reactions of 2-pyridinealdoxime [(py)CHNOH] with Ni(ClO₄)₂·6H₂O in the presence of NaOH and NaN₃ have led to Ni^II₁₄ and Ni^II₁₂Na₂ clusters; the Ni₁₄ compound is the biggest metal oxime cluster discovered to date, as well as the largest Ni azide cluster.

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Article information

DOI: https://doi.org/10.1039/B708189H
Article type: Communication
Submitted: 30 May 2007
Accepted: 16 Jul 2007
First published: 30 Jul 2007

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Dalton Trans., 2007, 3861-3863

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The highest nuclearity metal oxime clusters: Ni₁₄ and Ni₁₂Na₂ complexes from the use of 2-pyridinealdoximate and azide ligands

T. C. Stamatatos, K. A. Abboud, S. P. Perlepes and G. Christou, Dalton Trans., 2007, 3861 DOI: 10.1039/B708189H

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Dalton Transactions