Issue 40, 2007
From the journal:

Chemical Communications

Versatile direct dehydrative approach for diaryliodonium(iii) salts in fluoroalcohol media†

Toshifumi Dohi,a   Motoki Ito,a   Koji Morimoto,a   Yutaka Minamitsuji,a   Naoko Takenagaa  and  Yasuyuki Kita*a  

* Corresponding authors

a Graduate School of Pharmaceutical Sciences, Osaka University, 1-6 Yamada-oka, Suita, Osaka, Japan
E-mail: kita@phs.osaka-u.ac.jp
Fax: +81-6-6879-8229
Tel: +81-6-6879-8225

Abstract

We have found that the use of fluoroalcohol media greatly enhanced the efficiency and scope of the direct dehydrative condensation of arenes1 and hypervalent iodine(III) compounds; the present clean method has a broad range of applicability as well as unique selectivity in the aromatic substrates, and is highly efficient even in polymer functionalization.

Graphical abstract: Versatile direct dehydrative approach for diaryliodonium(iii) salts in fluoroalcohol media

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Article information

DOI
https://doi.org/10.1039/B708802G
Article type
Communication
Submitted
12 Jun 2007
Accepted
16 Jul 2007
First published
03 Aug 2007

Chem. Commun., 2007, 4152-4154

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Versatile direct dehydrative approach for diaryliodonium(III) salts in fluoroalcohol media

T. Dohi, M. Ito, K. Morimoto, Y. Minamitsuji, N. Takenaga and Y. Kita, Chem. Commun., 2007, 4152 DOI: 10.1039/B708802G

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