Issue 44, 2007
From the journal:

Chemical Communications

A highly efficient non-heme manganese complex in oxygenation reactions†

Kasi Nehru,a   Soo Jeong Kim,a   In Young Kim,a   Mi Sook Seo,a   Youngmee Kim,a   Sung-Jin Kim,a   Jinheung Kima  and  Wonwoo Nam*a  

* Corresponding authors

a Department of Chemistry, Division of Nano Sciences, and Center for Biomimetic Systems, Ewha Womans University, Seoul 120-750, Korea
E-mail: wwnam@ewha.ac.kr
Fax: 82 2 3277 4441
Tel: 82 2 3277 2392

Abstract

A non-heme manganese(II) complex shows a high catalytic activity in the epoxidation of olefins by iodosyl benzene and in the oxidation of olefins, alcohols and alkanes by peracetic acid; a mechanism involving metal-based oxidants is proposed for the oxidation reactions.

Graphical abstract: A highly efficient non-heme manganese complex in oxygenation reactions

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Article information

DOI
https://doi.org/10.1039/B708976G
Article type
Communication
Submitted
14 Jun 2007
Accepted
03 Sep 2007
First published
20 Sep 2007

Chem. Commun., 2007, 4623-4625

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A highly efficient non-heme manganese complex in oxygenation reactions

K. Nehru, S. J. Kim, I. Y. Kim, M. S. Seo, Y. Kim, S. Kim, J. Kim and W. Nam, Chem. Commun., 2007, 4623 DOI: 10.1039/B708976G

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