Issue 48, 2007
From the journal:

Chemical Communications

Catalytic hydrogenation of polar organic functionalities based on Ru-mediated heterolytic dihydrogen cleavage†‡

Masato Itoa  and  Takao Ikariya*a  

* Corresponding authors

a Department of Applied Chemistry, Tokyo Institute of Technology, Ookayama, Meguro, Tokyo 152-8552, Japan
E-mail: tikariya@apc.titech.ac.jp
Fax: 81 3 5734 2637
Tel: 81 3 5734 2636

Abstract

This article highlights Ru complexes, which effect catalytic hydrogenation of polar organic functionalities containing C–O bonds other than aldehydes or ketones. The unique ability of Ru complexes to undergo heterolytic dihydrogen cleavage seems to play a key role in these catalyses.

Graphical abstract: Catalytic hydrogenation of polar organic functionalities based on Ru-mediated heterolytic dihydrogen cleavage

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Article information

DOI
https://doi.org/10.1039/B709704B
Article type
Feature Article
Submitted
27 Jun 2007
Accepted
25 Jul 2007
First published
16 Aug 2007

Chem. Commun., 2007, 5134-5142

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Catalytic hydrogenation of polar organic functionalities based on Ru-mediated heterolytic dihydrogen cleavage

M. Ito and T. Ikariya, Chem. Commun., 2007, 5134 DOI: 10.1039/B709704B

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