Issue 6, 2008
From the journal:

Chemical Communications

Bowl-to-bowl inversion of sumanene derivatives†‡

Toru Amaya,a   Hiroyuki Sakane,a   Toshiko Muneishia  and  Toshikazu Hirao*a  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka, Japan
E-mail: hirao@chem.eng.osaka-u.ac.jp
Fax: +81-6-6879-7415
Tel: +81-6-6879-7413

Abstract

The bowl-to-bowl inversion of the non-planar bowl-shaped compounds derived from sumanene as a fullereneC3v fragment was found to be slow and tuned by a solvent, and the benzylic mono- and di-anions inverted even more slowly.

Graphical abstract: Bowl-to-bowl inversion of sumanene derivatives

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Article information

DOI
https://doi.org/10.1039/B712839H
Article type
Communication
Submitted
21 Aug 2007
Accepted
07 Nov 2007
First published
13 Dec 2007

Chem. Commun., 2008, 765-767

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Bowl-to-bowl inversion of sumanene derivatives

T. Amaya, H. Sakane, T. Muneishi and T. Hirao, Chem. Commun., 2008, 765 DOI: 10.1039/B712839H

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