Issue 2, 2008
From the journal:

Chemical Communications

Oxidation by CO2 of Au0 species on La2O3-supported gold clusters

Mihail Mihaylov,*ab   Elena Ivanova,ab   Yalin Hao,c   Konstantin Hadjiivanov,a   Bruce C. Gatesc  and  Helmut Knözingerb  

* Corresponding authors

a Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, Bulgaria
E-mail: misho@svr.igic.bas.bg
Fax: +359-2-8705024

b Department Chemie und Biochemie, Physikalische Chemie, Ludwig-Maximilians-Universität München, München, Germany

c Department of Chemical Engineering and Materials Science, University of California, Davis, One Shields Avenue, Davis, USA

Abstract

The IR spectra that characterize La2O3-supported gold clusters show that the original Au0 species can be oxidized by CO2 during the catalyticCO oxidation reaction, indicating that CO2 is the actual gold oxidizing agent.

Graphical abstract: Oxidation by CO2 of Au0 species on La2O3-supported gold clusters

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Article information

DOI
https://doi.org/10.1039/B713106B
Article type
Communication
Submitted
28 Aug 2007
Accepted
01 Oct 2007
First published
17 Oct 2007

Chem. Commun., 2008, 175-177

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Oxidation by CO2 of Au0 species on La2O3-supported gold clusters

M. Mihaylov, E. Ivanova, Y. Hao, K. Hadjiivanov, B. C. Gates and H. Knözinger, Chem. Commun., 2008, 175 DOI: 10.1039/B713106B

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