Intermolecular        radical        addition reactions of α-iodo cycloalkenones and a synthetic study of the formal synthesis of enantiopurefawcettimine

Kuan-Miao Liu; Chi-Min Chau; Chin-Kang Sha

doi:10.1039/B714078A

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Intermolecularradicaladdition reactions of α-iodo cycloalkenones and a synthetic study of the formal synthesis of enantiopurefawcettimine†

Kuan-Miao Liu,*^a Chi-Min Chau*^a and Chin-Kang Sha^b

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* Corresponding authors

^a School of Applied Chemistry, Chung Shan Medical University, Taiwan, ROC
E-mail: lkm@csmu.edu.tw, cmchau@csmu.edu.tw

^b Department of Chemistry, National Tsing Hua University, Taiwan, ROC

Abstract

The generation of α-carbonyl vinyl radicals from α-iodo cycloalkenones, the scope of their participation in intermolecularaddition reactions with electron-withdrawing olefins are studied and a synthetic study of the formal synthesis of enantiopurefawcettimine using this reaction is described.

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Article information

DOI: https://doi.org/10.1039/B714078A
Article type: Communication
Submitted: 12 Sep 2007
Accepted: 01 Oct 2007
First published: 21 Nov 2007

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Chem. Commun., 2008, 91-93

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Intermolecular radical addition reactions of α-iodo cycloalkenones and a synthetic study of the formal synthesis of enantiopurefawcettimine

K. Liu, C. Chau and C. Sha, Chem. Commun., 2008, 91 DOI: 10.1039/B714078A

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Chemical Communications