Issue 2, 2008

Chemo- and enantioselective sulfoxidation of bis(ethylenedithio)-tetrathiafulvalene (BEDT-TTF) into chiral BEDT-TTF-sulfoxide

Abstract

Selective sulfoxidation of BEDT-TTF (bis(ethylenedithio)-tetrathiafulvalene) with enantiopure (camphoryl-sulfonyl)oxaziridine derivatives provided the inner monosulfoxide, as demonstrated using single crystal X-ray analysis, with an enantiomeric excess of 44% (up to 74% after recrystallization).

Graphical abstract: Chemo- and enantioselective sulfoxidation of bis(ethylenedithio)-tetrathiafulvalene (BEDT-TTF) into chiral BEDT-TTF-sulfoxide

Supplementary files

Article information

Article type
Communication
Submitted
14 Sep 2007
Accepted
11 Oct 2007
First published
23 Oct 2007

Chem. Commun., 2008, 220-222

Chemo- and enantioselective sulfoxidation of bis(ethylenedithio)-tetrathiafulvalene (BEDT-TTF) into chiral BEDT-TTF-sulfoxide

M. Chas, M. Lemarié, M. Gulea and N. Avarvari, Chem. Commun., 2008, 220 DOI: 10.1039/B714245E

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