X-Ray structure of [ReCl4(μ-ox)Cu(pyim)2]: a new heterobimetallic ReIVCuII ferrimagnetic chain

José Martínez-Lillo; Donatella Armentano; Giovanni De Munno; Francesc Lloret; Miguel Julve; Juan Faus

doi:10.1039/B714563B

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X-Ray structure of [ReCl₄(μ-ox)Cu(pyim)₂]: a new heterobimetallic Re^IVCu^II ferrimagnetic chain†‡§

José Martínez-Lillo,^a Donatella Armentano,^b Giovanni De Munno,*^b Francesc Lloret,^a Miguel Julve^a and Juan Faus*^a

Author affiliations

* Corresponding authors

^a Departamento de Química Inorgánica/Instituto de Ciencia Molecular, Facultad de Química de la Universidad de Valencia, Dr. Moliner 50, Burjassot, Valencia, Spain
E-mail: juan.faus@uv.es, lillo@uv.es

^b Dipartimento di Chimica, Università della Calabria, via P. Bucci 14/c, Rende, Cosenza, Italy
E-mail: demunno@unical.it

Abstract

A new heterobimetallic Re^IVCu^II compound has been prepared and its crystal structure determined by single-crystal X-ray diffraction; magnetic susceptibility measurements show that this compound behaves as a ferrimagnetic chain with significant antiferromagnetic interactions between Re(IV) and Cu(II) metal ions.

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Article information

DOI: https://doi.org/10.1039/B714563B
Article type: Communication
Submitted: 20 Sep 2007
Accepted: 10 Oct 2007
First published: 29 Oct 2007

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Dalton Trans., 2008, 40-43

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X-Ray structure of [ReCl₄(μ-ox)Cu(pyim)₂]: a new heterobimetallic Re^IVCu^II ferrimagnetic chain

J. Martínez-Lillo, D. Armentano, G. De Munno, F. Lloret, M. Julve and J. Faus, Dalton Trans., 2008, 40 DOI: 10.1039/B714563B

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Dalton Transactions