Issue 3, 2008

Solvatomagnetic effect and spin-glass behavior in a 1D coordination polymer constructed from EE-azido bridged MnIII3O units

Abstract

The non-uniform chain manganese(III) complex constructed from EE-azido bridged MnIII3O units, [MnIII3O(Brppz)3(MeOH)3(N3)]·2MeOH [1, Brppz = 3-(5-bromo-2-phenolate)pyrazolate], is the first example of 1D azido-bridged coordination polymer showing both solvatomagnetic effect and spin-glass behavior.

Graphical abstract: Solvatomagnetic effect and spin-glass behavior in a 1D coordination polymer constructed from EE-azido bridged MnIII3O units

Supplementary files

Article information

Article type
Communication
Submitted
01 Oct 2007
Accepted
05 Nov 2007
First published
12 Nov 2007

Chem. Commun., 2008, 368-370

Solvatomagnetic effect and spin-glass behavior in a 1D coordination polymer constructed from EE-azido bridged MnIII3O units

C. Liu, D. Zhang and D. Zhu, Chem. Commun., 2008, 368 DOI: 10.1039/B715080F

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