Issue 1, 2008
From the journal:

Chemical Communications

Anti-Markovnikov hydroamination and hydrothiolation of electron-deficient vinylarenes catalyzed by well-defined monomeric copper(i) amido and thiolate complexes†

Colleen Munro-Leighton,a   Samuel A. Delp,a   Nikki M. Alsop,a   Elizabeth D. Bluea  and  T. Brent Gunnoe*a  

* Corresponding authors

a Department of Chemistry, North Carolina State University, Raleigh, USA
E-mail: brent_gunnoe@ncsu.edu
Fax: +1 919-515-8909
Tel: +1 919-513-3704

Abstract

Monomeric Cu(I) amido and thiolate complexes that are supported by the N-heterocyclic carbene ligand 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene (IPr) catalyze the hydroamination and hydrothiolation of electron-deficient vinylarenes with reactivity patterns that are consistent with an intermolecular nucleophilic addition of the amido/thiolate ligand of (IPr)Cu(XR) (X = NH or S; R = Ph, CH2Ph) to free vinylarene.

Graphical abstract: Anti-Markovnikov hydroamination and hydrothiolation of electron-deficient vinylarenes catalyzed by well-defined monomeric copper(i) amido and thiolate complexes

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Article information

DOI
https://doi.org/10.1039/B715507G
Article type
Communication
Submitted
08 Oct 2007
Accepted
11 Oct 2007
First published
24 Oct 2007

Chem. Commun., 2008, 111-113

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Anti-Markovnikov hydroamination and hydrothiolation of electron-deficient vinylarenes catalyzed by well-defined monomeric copper(I) amido and thiolate complexes

C. Munro-Leighton, S. A. Delp, N. M. Alsop, E. D. Blue and T. B. Gunnoe, Chem. Commun., 2008, 111 DOI: 10.1039/B715507G

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