Issue 3, 2008
From the journal:

Organic & Biomolecular Chemistry

Aminobromination of olefins with TsNH2 and NBS as the nitrogen and bromine sources mediated by hypervalent iodine in a ball mill

Xue-Liang Wu,a   Jing-Jing Xiaa  and  Guan-Wu Wang*a  

* Corresponding authors

a Hefei National Laboratory for Physical Sciences at Microscale, Joint Laboratory of Green Synthetic Chemistry, and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, People's Republic of China
E-mail: gwang@ustc.edu.cn
Fax: +86-551-360-7864

Abstract

A series of olefins including α,β-unsaturated ketones, cinnamates, cinnamides and styrenes have been aminobrominated with good yields and excellent diastereoselectivities under mechanical milling conditions, using TsNH2 and NBS as the nitrogen and bromine sources, promoted by (diacetoxyiodo)benzene.

Graphical abstract: Aminobromination of olefins with TsNH2 and NBS as the nitrogen and bromine sources mediated by hypervalent iodine in a ball mill

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Article information

DOI
https://doi.org/10.1039/B717333D
Article type
Paper
Submitted
08 Nov 2007
Accepted
29 Nov 2007
First published
18 Dec 2007

Org. Biomol. Chem., 2008,6, 548-553

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Aminobromination of olefins with TsNH2 and NBS as the nitrogen and bromine sources mediated by hypervalent iodine in a ball mill

X. Wu, J. Xia and G. Wang, Org. Biomol. Chem., 2008, 6, 548 DOI: 10.1039/B717333D

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