Issue 13, 2008

Are carbodiphosphoranes better ligands than N-heterocyclic carbenes for Grubb’s catalysts?

Abstract

Theoretical investigations suggest that substitution of an N-heterocyclic carbene by a carbodiphosphorane in the Grubb’s catalyst for olefin metathesis might lead to enhanced reactivity.

Graphical abstract: Are carbodiphosphoranes better ligands than N-heterocyclic carbenes for Grubb’s catalysts?

Supplementary files

Article information

Article type
Communication
Submitted
12 Nov 2007
Accepted
09 Feb 2008
First published
27 Feb 2008

Chem. Commun., 2008, 1584-1586

Are carbodiphosphoranes better ligands than N-heterocyclic carbenes for Grubb’s catalysts?

R. Tonner and G. Frenking, Chem. Commun., 2008, 1584 DOI: 10.1039/B717511F

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