Issue 13, 2008
From the journal:

Chemical Communications

Single-crystal-to-single-crystal transformation involving release of bridging water molecules and conversion of chain helicity in a chiral three-dimensional metal-organic framework†

Dong-Xu Xue,a   Wei-Xiong Zhang,a   Xiao-Ming Chen*ab  and  He-Zhou Wangb  

* Corresponding authors

a MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Guangzhou 510275, China
E-mail: cxm@mail.sysu.edu.cn
Fax: 86 20 8411-2245
Tel: 86 20 8411-2074

b State Key Laboratory of Optoelectronic Materials and Technologies, Sun Yat-Sen University, Guangzhou 510275, China

Abstract

An unprecedented release of the bridging aqua molecules and conversion of chain helicity within a 3-D chiral cadmium(II) dicarboxylate coordination polymer was observed in a unique and drastic single-crystal-to-single-crystal transformation of dehydration.

Graphical abstract: Single-crystal-to-single-crystal transformation involving release of bridging water molecules and conversion of chain helicity in a chiral three-dimensional metal-organic framework

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Article information

DOI
https://doi.org/10.1039/B717885A
Article type
Communication
Submitted
19 Nov 2007
Accepted
28 Jan 2008
First published
20 Feb 2008

Chem. Commun., 2008, 1551-1553

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Single-crystal-to-single-crystal transformation involving release of bridging water molecules and conversion of chain helicity in a chiral three-dimensional metal-organic framework

D. Xue, W. Zhang, X. Chen and H. Wang, Chem. Commun., 2008, 1551 DOI: 10.1039/B717885A

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