Issue 3, 2008
From the journal:

Organic & Biomolecular Chemistry

Highly efficient and stereoselective synthesis of β-glycolipids†

José Antonio Morales-Serna,a   Omar Boutureira,a   Yolanda Díaz,a   M. Isabel Matheua  and  Sergio Castillón*a  

* Corresponding authors

a Departamento de Química Analítica y Química Orgánica, Universitat Rovira i Virgili, C/Marcel.li Domingo s/n, 43007 Tarragona, Spain
E-mail: sergio.castillon@urv.net
Fax: +34 977 558446
Tel: + 34 977 559556

Abstract

β-Galactosylceramide and glycolipid analogues were prepared in high yield and with complete chemo and stereoselectivity by reaction of α-iodo glycosides with stannyl ceramides, formed in situ. TBAI was used to activate both the iodogalactose and the stannyl ether.

Graphical abstract: Highly efficient and stereoselective synthesis of β-glycolipids

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Article information

DOI
https://doi.org/10.1039/B718521A
Article type
Communication
Submitted
30 Nov 2007
Accepted
30 Nov 2007
First published
11 Dec 2007

Org. Biomol. Chem., 2008,6, 443-446

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Highly efficient and stereoselective synthesis of β-glycolipids

J. A. Morales-Serna, O. Boutureira, Y. Díaz, M. I. Matheu and S. Castillón, Org. Biomol. Chem., 2008, 6, 443 DOI: 10.1039/B718521A

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