Issue 21, 2008
From the journal:

Dalton Transactions

Electronic modification of an aminotroponiminate zinc complex leading to an increased reactivity in the hydroamination of alkenes†

Maximilian Dochnahl,a   Karolin Löhnwitz,b   Jens-Wolfgang Pissarek,a   Peter W. Roesky*b  and  Siegfried Blechert*a  

* Corresponding authors

a Technische Universität Berlin, Institut für Chemie, Straße des 17. Juni 135, Berlin, Germany
E-mail: blechert@chem.tu-berlin.de
Fax: +49 (0)30 3142 3619
Tel: +49 (0)30 3142 2355

b Freie Universität Berlin, Institut für Chemie und Biochemie, Fabeckstraße 34-36, Berlin, Germany
E-mail: roesky@chemie.fu-berlin.de
Fax: +49 (0)30 8385 2440
Tel: +49 (0)30 8385 4004

Abstract

The electronically modified zinc complex 5-phenylsulfanyl-N-isopropyl-2-(isopropylamino)troponiminate zinc methyl, [{PhS-ATI(iPr)2}ZnMe], was synthesized. It showed an increased reactivity in the intramolecular hydroamination reaction of non-activated alkenes compared to a previously-reported, non-substituted complex.

Graphical abstract: Electronic modification of an aminotroponiminate zinc complex leading to an increased reactivity in the hydroamination of alkenes

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Article information

DOI
https://doi.org/10.1039/B719120K
Article type
Paper
Submitted
11 Dec 2007
Accepted
04 Mar 2008
First published
04 Apr 2008

Dalton Trans., 2008, 2844-2848

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Electronic modification of an aminotroponiminate zinc complex leading to an increased reactivity in the hydroamination of alkenes

M. Dochnahl, K. Löhnwitz, J. Pissarek, P. W. Roesky and S. Blechert, Dalton Trans., 2008, 2844 DOI: 10.1039/B719120K

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