Issue 19, 2008
From the journal:

Chemical Communications

Unusual parallel and inclined interlocking modes in polyrotaxane-like metal–organic frameworks†

Jin Yang,a   Jian-Fang Ma,*a   Stuart R. Batten*b  and  Zhong-Min Sua  

* Corresponding authors

a Key Lab of Polyoxometalate Science, Department of Chemistry, Northeast Normal University, Changchun 130024, People’s Republic of China
E-mail: jianfangma@yahoo.com.cn
Fax: +86 431 85098620
Tel: +86 431 85098620

b School of Chemistry, Monash University, Victoria, Australia
E-mail: stuart.batten@sci.monash.edu.au
Fax: +61-3-9905-4597

Abstract

We describe here two unusual polyrotaxane-like metal–organic frameworks of [Co2(1,3-bix)2(bpea)2] 1 and [Cd4(1,4-bix)4(bpea)4]·4H2O 2, where both species contain loops and rods that are interlaced in a highly rare “parallel” fashion in 1, but, uniquely, in an “inclined” fashion in 2.

Graphical abstract: Unusual parallel and inclined interlocking modes in polyrotaxane-like metal–organic frameworks

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Article information

DOI
https://doi.org/10.1039/B800199E
Article type
Communication
Submitted
08 Jan 2008
Accepted
13 Feb 2008
First published
10 Mar 2008

Chem. Commun., 2008, 2233-2235

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Unusual parallel and inclined interlocking modes in polyrotaxane-like metal–organic frameworks

J. Yang, J. Ma, S. R. Batten and Z. Su, Chem. Commun., 2008, 2233 DOI: 10.1039/B800199E

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